Cohn, H. ``On the Simulated Annealing Chain.'' Statistics Department Research Report #1, 1995 Abstract Cooling schedules of the form $\{c/{\log(k+1)}\}$, where $c$ is a sufficiently large constant, have proven necessary for convergence of the simulated annealing algorithm to the set of global minima. Independence of the initial state and ability of the system to escape from any set are often considered desirable attributes. It is known that such properties hold for $c$ large enough. However, there are convergent algorithms characterised by traps which are not asymptotically independent. It is shown that a finely tuned cooling schedule renders a maximal set of states transient and has one or more friendly "traps" leading to global minima. The performance of the algorithm relies heavily on the value of $c$ for which the process exhibits phase transitions.